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投稿时间:2018-07-09
投稿时间:2018-07-09
中文摘要: 建立采用氧弹燃烧-离子色谱法测定婴儿配方奶粉中的氯含量的条件及方法。以氧弹对婴儿配方奶粉试样进行燃烧,10 mmol/L NaOH为吸收液进行吸收,以Dionex IonPac AS 11-HC柱,KOH梯度淋洗,流速为1.0 mL/min。经离子色谱分离测定婴儿配方奶粉中的氯的含量。氯离子的方法检出限为13.2 μg/L。利用该方法对婴儿配方奶粉中的氯进行测定,线性相关系数为0.999 9,平均回收率为91.0%~95.5%,相对标准偏差为1.9%~3.5%。
Abstract:The determination method of chlorine in infant formula milk powder by oxygen bomb comustion-ion chromatography and 10 mmol/L NaOH as the absorption solution was investigated.All species were separated at Dionex IonPac AS 11-HC column with mobile phase of KOH at a flow-rate of 1.0 mL/min.The detection limit of chloridion was 13.2 μg/L.The proposed method was used to determinate the chlorine in infant formula milk powder samples,the correlation coefficient was 0.999 9,the recoveries of the anions were in the range of 91.0%-95.5%,the relative standard deviations of chlorine were 1.9%-3.5%。
keywords: oxygen bomb combustion ion chromatography infant formula milk powder chlorine determination
文章编号:201905032 中图分类号: 文献标志码:
基金项目:国家质量监督检验检疫总局科技计划项目(2016IK252)
Author Name | Affiliation |
ZHANG Hua,CHEN Xu-yan,CHEN Wen-shuo | Animal&Plant and Food Inspection Center of Tianjin Customs(Former Tianjin Ispection and Quarantine Bureau),Tianjin 300461,China |
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